Bond which is formed by sidewise overlapping of $2p$-orbitals of chalcogen atom is present in :

Which of the following represents the most effective overlapping?

Explain the characteristics of $\pi$ bonds. Or,give the requirements for the formation of $\pi$ bonds and explain the active centers.

Distinguish between a sigma and a pi bond.

Match the orbital overlap figures shown in List-$I$ with the description given in List-$II$ and select the correct answer using the code given below the lists.
List-$I$:
$P$. Two $d$-orbitals overlapping axially with same phase.
$Q$. $A$ $p$-orbital and a $d$-orbital overlapping laterally with same phase.
$R$. $A$ $p$-orbital and a $d$-orbital overlapping laterally with opposite phase.
$S$. Two $d$-orbitals overlapping axially with opposite phase.
List-$II$:
$1$. $p-d$ $\pi$ antibonding
$2$. $d-d$ $\sigma$ bonding
$3$. $p-d$ $\pi$ bonding
$4$. $d-d$ $\sigma$ antibonding
Codes: $P \quad Q \quad R \quad S$

Number of $\sigma$ (sigma) and $\pi$ (pi) bonds in aspirin are respectively . . . . . . .